If you don't have the chamber wall opened up, in many cases you will net less flow with a larger valve. I would prefer to see you unshroud the valves and do a better valvejob with throat, front, and back cuts and/or pocket porting. IMHO that's a better way to go, but then again, I live on my flowbench.
If you flow the port, and then reflow it with the bigger valve, it will show how much you will lose to shrouding. Then have someone that knows Buick heads give you a pro opinion. Or just talk to a Buick head porter first.
The #1 mistake most make is in assuming the port stops at the valve seat. If you treat the chamber as an important part of the flow path you are ahead of the game.
P.S. you did have the intake manifold ported, and entire EGR setup in the plenum removed first didn't you?
TIMINATOR