For 91 octane, I believe your chip is set to 17/15 low gear/high gear timing. Well for 100 octane I would advance the base timing 8 degrees for starters and not change the WOT timing. That would put you at 25/23. If all is OK at that point, maybe fiddle with WOT with another 2 degrees advance. All depends on the boost you're running. If you're running high boost (say 24lbs or more) you may want to advance the timing a little bit less and if running low boost, advance the timing a little more.
For C16, I'd advance the base timing 12 degrees (or is 10 the most you can do?) and go from there. Again, if you're not knocking with the boost you're running, maybe advance WOT another 2 degrees.
Good luck and remember that all cars are different and you may find that your car likes more of less timing then the next guy. Just use what I wrote above as guidance and ballpark figures.