LEGACY_GN
Active Member
- Joined
- Apr 16, 2007
As part of an effort to reduce vehicle emissions, the U.S. EPA offers vehicle manufacturers "credits" for early implementation as well as penalties for violation of emission reduction standards. The EPA's program called for 100,000-mile catalytic converter life by 2004, 120,000 miles by 2007, and 150,000 miles by 2009. To achieve these goals, automotive manufacturers have pressured their oil suppliers to remove substances from motor oils that would shorten the service life, including the proven EP (extreme pressure) additive ZDDP (zinc dialkyldithiophosphate). Zinc and phosphorus from the ZDDP can be present in small amounts in the exhaust gas of an engine depending on the amount of oil which is consumed in combustion. These elements can coat the catalyst reducing the amount of catalyst exposed to the exhaust gases, ultimately increasing emissions at the tailpipe. As a result of the EPA mandate, the ZDDP level in engine oils has been declining since the mid-1990s, roughly coinciding with the implementation of OBDII.
ZDDP has been an important additive to engine oils for over 70 years, and has an excellent track record at protecting the sliding metal-to-metal cam lifter interface. Historically, ZDDP has been added to oils in amounts resulting in approximately 0.15% phosphorus, and 0.18% zinc. ZDDP protects by creating a film on cams and flat lifter contact points in response to the extreme pressure and heat at the contact point. The film of zinc and phosphorus compounds provides a sacrificial wear surface protecting the base metal of the cam and lifter from wear. In the course of normal service, this conversion of ZDDP to zinc and phosphorus compounds depletes the ZDDP level in the oil. Studies show that depending on the specific engine and severity of duty, after 2000-4000 miles of operation, the level of ZDDP can drop below that considered adequate to provide wear protection to the cam and lifters.
According to the SAE Tech Bulletin # 770087 [1] , operation of a flat tappet engine without adequate EP additives such as ZDDP quickly leads to lifter foot scuffing and cam lobe wear. Camshafts are typically only surface hardened leaving the core ductile for strength. According to the SAE Bulletin, once cam lobe wear reaches 0.0002, "subsequent wear is usually rapid and catastrophic." Two ten-thousandths of an inch is one fifth the thickness of an average human hair.
In order to make engines last in the absence of ZDDP, virtually all IC (internal combustion) engines designed in the last ten years utilize roller lifters. Today, ZDDP has been removed from practically all automotive engine oils, rendering them unsuitable for use with older engines with non-roller lifters.
Why is it being removed?
Because contemporary engines with roller bearings no longer require the additional protection of Zinc and Phosphorus. Not true for classic cars, tractors, muscle cars, etc. Also removing the Zinc and Phosphorus from motor oil increases the life of the catalytic converter. But classic cars, tractors, etc., don’t have cats! Also, as part of its ongoing effort to reduce vehicle emissions, the EPA has mandated that emission systems must have a service life exceeding 120,000 miles. To achieve this, automotive manufacturers have required oil suppliers to remove additive packages from motor oils that could reduce emissions compliance.
ZddPlus is the ONLY EP (Extreme Pressure) component which re-establishes the ZDDP levels that our classic car engines were designed for, while allowing the car owner to use the base oil of their choice. While some off-the-shelf additives may have some ZDDP, the amount per bottle is small, and when enough is used to get the proper concentration of ZDDP, there is a quart or more of unspecified oil that comes along with it. This dilution of 20% of your oil with an unspecified oil also means that there is 20% less of the proper additive package. The chart below compares the amount of ZDDP in ZddPlus to GM EOS, an additive which claims to provide ZDDP based wear protection.
[1] Pless, Loren G., and Rodgers, John J., ‘Cam and Lifter Wear as Affected by Engine Oil ZDP Concentration and Type’, SAE pub 770087, 4
What's In Our Oil ?
As lubrication technology improves, so does the base oil used in the manufacture of engine oils. Oils are also changed and updated in response to advancements in engine technology.
Modern engine oil is a precise mix of a base oil with additives totaling almost 10% of the oil by volume. Pound for pound these additives are each more expensive than the base oil, and oil companies are in business to make a profit. Common sense says that these additives are there with good reason.
Modern engine oil is a multi-purpose fluid in an engine, carrying the heat away from hot spots and releasing it in the sump as well as providing lubrication to critical areas which need protection against wear. Different additives are put in the oil in order to address the needs of each specific engine system that is supplied with oil:
The crankshaft and connecting rod bearings discharge oil into the spinning reciprocating assembly, and an anti-foaming additive keeps the oil from turning into foam.
The heat developed on high-pressure contact areas can exceed the breakdown temperature rating of the base stock, so heat stabilizers are added in order to fight viscosity breakdown and ashing.
In a multi-viscosity oil, the multi-viscosity characteristic is established by an additive.
Acids and byproducts of combustion are neutralized by another additive.
A dispersant additive helps keep combustion particulates from clumping.
Detergents are added to lower the surface tension to a specific value to help keep contaminants in suspension and off of the metal engine parts. Some detergents also interact with the EP additive to gain an additional level of wear protection.
The sliding cam-to-cam-follower interface in a non-roller lifter engine requires a special EP additive, which has historically been the ZDDP that is now reduced in all API rated automotive oils.
ZddPlus contains the proper amount of ZDDP to give at least 0.18% zinc and 0.13% phosphorus level when a single 4 oz. bottle is added to a normal 5-quart oil change. This level of zinc and phosphorus is the level designed into pre-OBDII oils. Using ZddPlus affords you total control over the characteristics of the oil in the engine by allowing you to use the full 5 quarts of a high-grade automotive oil of your choice..
Why Can't We Use Diesel CI/CJ-4 Rated Oils?
There are some diesel engine rated oils on the market which may still have some ZDDP in them. There are problems associated with using these oils in a normal gasoline engine which can become severe in a high-performance gasoline engine. One issue is the high amount of detergent additive, and another is the high viscosity.
High detergent oil has a lower surface tension and lower shear pressure rating which can cause higher bearing wear in gas engines. A diesel engine needs oil with very high detergent capabilities in order to hold the large amount of combustion byproducts in suspension, but it is not optimized for a gasoline engine. The bearing journal size-to-displacement ratio on a gasoline engine is designed around the use of a lower detergent oil and relies on a high-shear rating to the oil.
The other problem with high detergent oil is that it actually reduces the friction reduction that the ZDDP affords, especially in a high-performance, high valve spring pressure engine.
The viscosity rating of most diesel rated oils is higher than optimum for our higher revving gasoline engines, and can cause oil starvation in bearings at high rpms.
Why Can't We Use Racing Oils?
There are some racing oils which maintain a level of ZDDP. Racing oils are optimized for short term severe duty, in contrast to an oil that has been designed for day in, day out street operation. The additive package in a racing oil does not have the same detergent characteristics which are designed into extended service oils. As a result, racing oils may not have the capability of neutralizing acids and keeping contaminants in suspension. Also, the breadth of choice of viscosity, so important to correct street engine operation over a broad temperature range, is not available in racing oils.
By using ZddPlus in addition to a modern high-quality oil of the proper viscosity for your gasoline engine, the correct EP lubrication level is established, and the oil characteristics remain optimized for your engine.r engine.
ZDDP has been an important additive to engine oils for over 70 years, and has an excellent track record at protecting the sliding metal-to-metal cam lifter interface. Historically, ZDDP has been added to oils in amounts resulting in approximately 0.15% phosphorus, and 0.18% zinc. ZDDP protects by creating a film on cams and flat lifter contact points in response to the extreme pressure and heat at the contact point. The film of zinc and phosphorus compounds provides a sacrificial wear surface protecting the base metal of the cam and lifter from wear. In the course of normal service, this conversion of ZDDP to zinc and phosphorus compounds depletes the ZDDP level in the oil. Studies show that depending on the specific engine and severity of duty, after 2000-4000 miles of operation, the level of ZDDP can drop below that considered adequate to provide wear protection to the cam and lifters.
According to the SAE Tech Bulletin # 770087 [1] , operation of a flat tappet engine without adequate EP additives such as ZDDP quickly leads to lifter foot scuffing and cam lobe wear. Camshafts are typically only surface hardened leaving the core ductile for strength. According to the SAE Bulletin, once cam lobe wear reaches 0.0002, "subsequent wear is usually rapid and catastrophic." Two ten-thousandths of an inch is one fifth the thickness of an average human hair.
In order to make engines last in the absence of ZDDP, virtually all IC (internal combustion) engines designed in the last ten years utilize roller lifters. Today, ZDDP has been removed from practically all automotive engine oils, rendering them unsuitable for use with older engines with non-roller lifters.
Why is it being removed?
Because contemporary engines with roller bearings no longer require the additional protection of Zinc and Phosphorus. Not true for classic cars, tractors, muscle cars, etc. Also removing the Zinc and Phosphorus from motor oil increases the life of the catalytic converter. But classic cars, tractors, etc., don’t have cats! Also, as part of its ongoing effort to reduce vehicle emissions, the EPA has mandated that emission systems must have a service life exceeding 120,000 miles. To achieve this, automotive manufacturers have required oil suppliers to remove additive packages from motor oils that could reduce emissions compliance.
ZddPlus is the ONLY EP (Extreme Pressure) component which re-establishes the ZDDP levels that our classic car engines were designed for, while allowing the car owner to use the base oil of their choice. While some off-the-shelf additives may have some ZDDP, the amount per bottle is small, and when enough is used to get the proper concentration of ZDDP, there is a quart or more of unspecified oil that comes along with it. This dilution of 20% of your oil with an unspecified oil also means that there is 20% less of the proper additive package. The chart below compares the amount of ZDDP in ZddPlus to GM EOS, an additive which claims to provide ZDDP based wear protection.
[1] Pless, Loren G., and Rodgers, John J., ‘Cam and Lifter Wear as Affected by Engine Oil ZDP Concentration and Type’, SAE pub 770087, 4
What's In Our Oil ?
As lubrication technology improves, so does the base oil used in the manufacture of engine oils. Oils are also changed and updated in response to advancements in engine technology.
Modern engine oil is a precise mix of a base oil with additives totaling almost 10% of the oil by volume. Pound for pound these additives are each more expensive than the base oil, and oil companies are in business to make a profit. Common sense says that these additives are there with good reason.
Modern engine oil is a multi-purpose fluid in an engine, carrying the heat away from hot spots and releasing it in the sump as well as providing lubrication to critical areas which need protection against wear. Different additives are put in the oil in order to address the needs of each specific engine system that is supplied with oil:
The crankshaft and connecting rod bearings discharge oil into the spinning reciprocating assembly, and an anti-foaming additive keeps the oil from turning into foam.
The heat developed on high-pressure contact areas can exceed the breakdown temperature rating of the base stock, so heat stabilizers are added in order to fight viscosity breakdown and ashing.
In a multi-viscosity oil, the multi-viscosity characteristic is established by an additive.
Acids and byproducts of combustion are neutralized by another additive.
A dispersant additive helps keep combustion particulates from clumping.
Detergents are added to lower the surface tension to a specific value to help keep contaminants in suspension and off of the metal engine parts. Some detergents also interact with the EP additive to gain an additional level of wear protection.
The sliding cam-to-cam-follower interface in a non-roller lifter engine requires a special EP additive, which has historically been the ZDDP that is now reduced in all API rated automotive oils.
ZddPlus contains the proper amount of ZDDP to give at least 0.18% zinc and 0.13% phosphorus level when a single 4 oz. bottle is added to a normal 5-quart oil change. This level of zinc and phosphorus is the level designed into pre-OBDII oils. Using ZddPlus affords you total control over the characteristics of the oil in the engine by allowing you to use the full 5 quarts of a high-grade automotive oil of your choice..
Why Can't We Use Diesel CI/CJ-4 Rated Oils?
There are some diesel engine rated oils on the market which may still have some ZDDP in them. There are problems associated with using these oils in a normal gasoline engine which can become severe in a high-performance gasoline engine. One issue is the high amount of detergent additive, and another is the high viscosity.
High detergent oil has a lower surface tension and lower shear pressure rating which can cause higher bearing wear in gas engines. A diesel engine needs oil with very high detergent capabilities in order to hold the large amount of combustion byproducts in suspension, but it is not optimized for a gasoline engine. The bearing journal size-to-displacement ratio on a gasoline engine is designed around the use of a lower detergent oil and relies on a high-shear rating to the oil.
The other problem with high detergent oil is that it actually reduces the friction reduction that the ZDDP affords, especially in a high-performance, high valve spring pressure engine.
The viscosity rating of most diesel rated oils is higher than optimum for our higher revving gasoline engines, and can cause oil starvation in bearings at high rpms.
Why Can't We Use Racing Oils?
There are some racing oils which maintain a level of ZDDP. Racing oils are optimized for short term severe duty, in contrast to an oil that has been designed for day in, day out street operation. The additive package in a racing oil does not have the same detergent characteristics which are designed into extended service oils. As a result, racing oils may not have the capability of neutralizing acids and keeping contaminants in suspension. Also, the breadth of choice of viscosity, so important to correct street engine operation over a broad temperature range, is not available in racing oils.
By using ZddPlus in addition to a modern high-quality oil of the proper viscosity for your gasoline engine, the correct EP lubrication level is established, and the oil characteristics remain optimized for your engine.r engine.
