The 25 Amp. A/C fuse runs the following circuits:
It doesn't have anything to do with the powermaster.
It is hot in RUN only, as is the RLYS fuse and the WDO circuit breaker.
If you just redo that wiring, which is what I would recommend, make sure those two previously mentioned circuits work okay and aren't melted in any way.
Make sure you get a feed for the new wiring from a source on the IGN switch that is hot in RUN only, through a new fuse, an in-line holder should work just fine rated at 25A.
The A/C fuse runs IGN 3 so don't use that slot in the fuse panel!
It also runs the trunk release switch, and the A/C control head for manual or automatic A/C and the blower switch feed. Not too many branch circuits and wiring is mostly brown in color.
It should be relatively easy to fix I would think if you can access to the wiring.