Do this: at key-on, engine-off observe the check engine light (CEL), it should turn on, blink off, then turn on solid. Can repeat the test after a minimum of 10 seconds of key-off.
The key is: the CEL must do the blink off.
If it doesn't don't bother to turn the key to start, the ECM is in limp mode. Which is why it is so rich, the back up fueling is calibrated for the stock injectors. Not the larger ones you'all are running.
If you have a PL installed, remove it and do the blink test again.
Further troubleshooting for the 'no CEL blink' is another chip and then another ECM.
RemoveBeforeFlight
I notice the Dynamic EFI ad on you page, could you expand on it's use with turbo buicks, please