Correct me if I'm correct, but I think the headers in our GNs and Turbo Ts are made of of mild stainless steel, 409 type. They don't hold up too well over a LONG period of time and also have a tendency to rust a little.....
You are correct, they are 409, but for them to be called stainless is bogus!
Just put a magnet to a stock header to confirm that.
After almost 25 years of heat cycles, poor material, bad design, the stock headers are about done. Welding helps crystalize the 409 even further, so they crack at the repair weld next time.
Using a TIG is a good idea because it usually uses less heat, but as far as an exotic rod material, you are just welding plain old steel.
I am not an expert on headers, but have a lot of experience with the turbo Buicks in helping to develop the TA headers, and other custom built turbo headers for race application, and street exotics like BMW, Mercedes, CTSV, and a few others done at my friend's fab shop.
Here is our most recent Buick headers done in 321 stainless for my race car.