For the vast majority of retail sites, E85 is blended at the fuel terminal and in the underground storage tank at the station. E20 and E30 would be blended by the dispesner using the 87 regular (E10) and E85.
E20 would be 89 octane and E30 about 91.
Where are you getting your octane information from?
Using a race gas mixing calculator heres what I have found. Ethanol according to wikipedia is 116 octane. I was told when calculating E85 this is not the value to use. Actual readings should be (R+M)/2. I was told to use 113 for ethanol octane rating when mixing ethanol fuels.
So mixing 3 gallons of 113 with 7 gallons 87. I come up with 94.8 octane. This would be a 30% mix (E30). 92.2 (E20) 89.8 (e10). If anything these numbers are conservatively low. Seeing as most 91 octane (around here anyway) contains 10% ethanol (e10).
I have since my original post converted my DD 1993 eagle talon turbo AWD to e30.
It can be done with very minimal effort. My chip was burnt for 11:1 AFR's @ WOT and 17* total timing under boost. The ONLY thing I did to run e30 was up my base fuel pressure from 37psi(Stock) To 43psi.
Pre e30 I was able to run 20lbs of boost @ 17* timing. I did run a 7gph 100% meth inj on top of this. Without it I would see knock at 17+psi.
With e30 I run 20* total timing and 25psi. 50/50 mix of meth/water. Zero knock. High and low fuel trims are at 100 (meaning ECU is not adding or removing fuel.
The only issue I've had is my idle fuel trims are now maxed out (139). Once warm, idle is still between 14.5-15.5 AFR's. On initial start the car does require me to slightly depress the pedal and hold it for the first minute or two. Once warmed up the car idles/drives/boosts as normal.
This upcoming spring I plan on starting out with e20 in the buick. Possibly making my way up to e30.
Hope this helps someone.