Boost doesn't have a lot to do with the octane of the fuel......my car may make 500 hp at 20 lbs boost and you may need 25 lbs boost to make the same power......so, the important thing is do you have enough octane, fuel volume, and the right timing to support the power you are trying to make.....
guess wrong, and you detonate, and that can happen at any boost level
jus because you have C16 doesn't mean you can run "X" amount of boost.....all depends on the combo & tune