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just got done doing a 350 same idea, sounds as if when the spring broke it dropped the valve low enough that it contacted the piston head, i have never seen this wreck a piston yet, so you are probably safe in that region, you will have to buy a new valve seeing i am pretty much 100% sure the valve is bent, and pull the intake and head off to get the valve out you should only have to tap it out with a hammer and put in the new one, and mate the new seat and valve together know as "valve lapping". then install the spring and retainers with a valve spring tool. clean all the head and intake surfaces, install the new head gasket, torque the head down in sequence, then install the intake with the gaskets facing the right way.
,Dan
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1985 Buick Grand National: 78,000 miles. 25 PSI  , Got rid of the alky now running E85 with a lot of success, Intercooled, complete engine back ceramic coated ATR Stainless Exhaust, going to TA-49 turbo, UMI suspension, Ported: large valve heads/intake, 42.5# inj., 3.5"intake/K&N, 3.5" LS-1 MAF& translator, 87 ecm, heater/AC delete, hotwired Walbro 340, elect. fans, Eric Marshal chip, Brian H built Trans with brake,3100 stall L/U Art Carr, deleted smog, ARP studs, To much little stuff to list..
1999 GMC Sierra Z71: EFI Live Programmer, small mods.
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